Difference between revisions 6001603 and 6001604 on simplewiki

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User:Barras/Ferrocene
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| Watchedfields = changed
| verifiedrevid = 310175235
| ImageFileL1 = Ferrocene-2D.png
| ImageSizeL1 = 80 px
| ImageFileR1 = Ferrocene-from-xtal-3D-balls.png
| ImageSizeR1 = 120 px
| ImageFile2 = Photo of Ferrocene (powdered).JPG
(contracted; show full)

The carbon atoms can be replaced by heteroatoms as illustrated by Fe(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)(η<sup>5</sup>-P<sub>5</sub>) and Fe(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(η<sup>5</sup>-C<sub>4</sub>H<sub>4</sub>N) ("[[azaferrocene]]"). 
The latterAzaferrocene arises from decarbonylation of Fe(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(CO)<sub>2</sub>(η<sup>1</sup>-pyrrole) in [[cyclohexane]].<ref>{{cite journal|doi=10.1016/0022-328X(90)85359-7|title=An improved photochemical synthesis of azaferrocene|year=1990|last1=Zakrzewski|first1=J|journal=Journal of Organometallic Chemistry|volume=388|pages=175}}</ref> This compound on boiling under [[reflux]] in [[benzene]] is converted to ferrocene.&l(contracted; show full)[[pl:Ferrocen]]
[[ru:Ферроцен]]
[[fi:Ferroseeni]]
[[sv:Ferrocen]]
[[th:เฟอร์โรซีน]]
[[tr:Ferrosen]]
[[ur:Ferrocene]]
[[zh:二茂铁]]