Difference between revisions 6001666 and 6001667 on simplewiki

{{chembox
| verifiedrevid = 396489042
| ImageFileL1 = Ferrocene.svg
| ImageSizeL1 = 80 px
| ImageFileR1 = Ferrocene-from-xtal-3D-balls.png
| ImageSizeR1 = 120 px
| ImageFile2 = Photo of Ferrocene (powdered).JPG
| ImageSize2 = 220 px
(contracted; show full)iversity]] reported the reaction of cyclopentadienyl magnesium bromide and [[iron(III) chloride|ferric chloride]] with the goal of oxidatively coupling the diene to prepare [[fulvalene]]. Instead, they obtained a light orange powder of "remarkable stability."<ref name = "Pauson_Kealy">{{cite journal |author = T. J. Kealy, P. L. Pauson |title = A New Type of Organo-Iron Compound |journal = [[Nature (journal)|Nature]] |year = 1951 |volume = 168 |pages = 1039 |doi = 10.1038/1681039b0
 |issue=4285}}</ref><ref>A second group independently discovered ferrocene.  See:  S. A. Miller, J. A. Tebboth, and J. F. Tremaine (1952) "Dicyclopentadienyliron," ''Journal of the Chemical Society'' (London) , pages 632-635.  See also:  Pierre Laszlo and Roald Hoffmann (2000) "[http://www.roaldhoffmann.com/pn/modules/Downloads/docs/Ferrocene.pdf Ferrocene:  Ironclad History of Rashomon Tale?]," ''Angewandte Chemie'' (International Edition), vol. 3(contracted; show full)
*{{cite journal |author=[[Ernst Otto Fischer|Fischer, E. O.]], Pfab, W.|title=Cyclopentadien-Metallkomplexe, ein neuer typ metallorganischer Verbindungen |journal=Z. Naturforsch. B|year=1952| volume=7 |pages=377–379}}
;Others
*{{cite journal|author=Dunitz, J. D., Orgel, L. E.|title=Bis-Cyclopentadienyl - A Molecular Sandwich|journal= [[Nature (journal)|Nature]] |year=1953| volume=171 |pages= 121–122|doi = 10.1038/171121a0
|issue=4342}}
*{{cite journal|author=Pauson, P. L.|title=Ferrocene-how it all began|journal=[[Journal of Organometallic Chemistry|J. Organomet. Chem.]]|year=2001|pages=637–639|volume = 637-639|doi = 10.1016/S0022-328X(01)01126-3}}
*{{cite book|author= Gerard Jaouen (ed.)| title=Bioorganometallics: Biomolecules, Labeling, Medicine| publisher=Wiley-VCH| location= Weinheim| year= 2006|isbn=978-3-527-30990-0}} (discussion of biological role of ferrocene and related compounds)
*University of Nottingham Molecular Videos, [http://www.periodicvideos.com/videos/mv_ferrocene.htm "Ferrocene"]

[[Category:Organoiron compounds]]
[[Category:Metallocenes]]
[[Category:Antiknock agents]]
[[Category:Sandwich compounds]]
[[Category:Cyclopentadienyl complexes]]

[[cs:Ferrocen]]
[[de:Ferrocen]]
[[es:Ferroceno]]
[[fr:Ferrocène]]
[[it:Ferrocene]]
[[nl:Ferroceen]]
[[ja:フェロセン]]
[[pl:Ferrocen]]
[[pt:Ferroceno]]
[[ru:Ферроцен]]
[[fi:Ferroseeni]]
[[sv:Ferrocen]]
[[th:เฟอร์โรซีน]]
[[tr:Ferrosen]]
[[uk:Фероцен]]
[[ur:Ferrocene]]
[[zh:二茂铁]]