Difference between revisions 6001714 and 6001715 on simplewiki

{{chembox
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| ImageFileL1 = Ferrocene.svg
| ImageSizeL1 = 80 px
| ImageFileR1 = Ferrocene-from-xtal-3D-balls.png
| ImageSizeR1 = 120 px
| ImageFileL2 = Ferrocene 3d model 2.png
(contracted; show full) |journal = Angewandte Chemie International Edition |year = 2000 |volume = 39 |pages = 123–124 |doi = 10.1002/(SICI)1521-3773(20000103)39:1<123::AID-ANIE123>3.0.CO;2-Z |pmid=10649350|issue = 1}}</ref><ref>Werner, H. (2012), At Least 60 Years of Ferrocene: The Discovery and Rediscovery of the Sandwich Complexes. Angew. Chem. Int. Ed., 51: 6052–6058. {{doi|10.1002/anie.201201598}}</ref> The stability of the new organoiron compound was accorded to the aromatic character of the negative
ly charged cyclopentadienyls, but they were not the ones to recognize the η<sup>5</sup> (pentahapto) sandwich structure.

[[Robert Burns Woodward]] and [[Geoffrey Wilkinson]] deduced the structure based on its reactivity.<ref>{{cite journal |author = G. Wilkinson, M. Rosenblum, M. C. Whiting, R. B. Woodward |title = The Structure of Iron Bis-Cyclopentadienyl |journal = [[Journal of the American Chemical Society]] |year = 1952|volume = 74 |pages = 2125–2126 |doi = 10.1021/ja01128a527 |issue =(contracted; show full)
[[josiphos ligands]]

[[Category:Organoiron compounds]]
[[Category:Metallocenes]]
[[Category:Antiknock agents]]
[[Category:Sandwich compounds]]
[[Category:Cyclopentadienyl complexes]]