Difference between revisions 6001765 and 6001766 on simplewiki

< previous diff
next diff >
User:Barras/Ferrocene
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 457631192
| ImageFileL1 = Ferrocene.svg
| ImageSizeL1 = 80 px
| ImageFileR1 = Ferrocene-from-xtal-3D-balls.png
| ImageSizeR1 = 80 px
(contracted; show full)

:6&nbsp;C<sub>5</sub>H<sub>5</sub>MgBr  +  2&nbsp;FeCl<sub>3</sub>   →   2&nbsp;Fe(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>  +  6&nbsp;MgBrCl  +  2&nbsp;
"('''([[C5H5|C<sub>5</sub>H<sub>5</sub>]])<sub>2</sub>"'''

Numerous other syntheses have been reported, including the direct reaction of [[gas]]-phase cyclopentadiene with metallic iron<ref>{{cite journal|doi=10.1021/ja01636a080|title=Bis-cyclopentadienyl Compounds of Nickel and Cobalt|year=1954|last1=Wilkinson|first1=G.|authorlink1=Geoffrey Wilkinson|last2=Pauson|first2=P. L.|last3=Cotton|first3=F. A.|authorlink3=F. Albert Cotton|journal=[[J. Am. Chem. Soc.]]|volume=76|pages=1970|issue=7}}</ref> at 350&nbsp;°C or with [[iron pentacarbonyl]].<r(contracted; show full)
{{Authority control}}

[[Category:Organoiron compounds]]
[[Category:Metallocenes]]
[[Category:Antiknock agents]]
[[Category:Sandwich compounds]]
[[Category:Cyclopentadienyl complexes]]