Difference between revisions 6001794 and 6001795 on simplewiki

{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 457631192
| ImageFileL1 = Ferrocene.svg
| ImageSizeL1 = 80 px
| ImageFileR1 = Ferrocene-from-xtal-3D-balls.png
| ImageSizeR1 = 80 px
(contracted; show full)st5=J.|last6=Dive|first6=D.|title=The antimalarial ferroquine: from bench to clinic|journal=Parasite|volume=18|issue=3|year=2011|pages=207–214|issn=1252-607X|doi=10.1051/parasite/2011183207|url=http://www.parasite-journal.org/articles/parasite/full_html/2011/03/parasite2011183p207/parasite2011183p207.html|PMID=21894260|PMC=3671469}} {{open access}}</ref><ref>Roux, C.; Biot, C., "Ferrocene-based antimalarials", Future Med. Chem. 2012, 4, 783-797. {{DOI|10.4155/fmc.12.26}}</ref>


===Batteries===
By functionalizing ferrocene molecules to turn the insoluble molecule into soluble bis((3-trimethylammonio)propyl)ferrocene dichloride,<ref>Eugene S. Beh, Diana De Porcellinis, Rebecca L. Gracia, Kay T. Xia, Roy G. Gordon, and Michael J. Aziz, [http://pubs.acs.org/doi/abs/10.1021/acsenergylett.7b00019 "A Neutral pH Aqueous Organic–Organometallic Redox Flow Battery with Extremely High Capacity Retention"], ''ACS Energy Lett., 2'', February 7, 2017, pp 639–644.  DOI: 10.1021/acsenergylett.7b00019. Retrieved 13 February 2017.</ref> ferrocene has been proposed to be used as a component of the electrolyte for a [[flow battery]].<ref>Leah Burrows, [http://www.seas.harvard.edu/news/2017/02/long-lasting-flow-battery-could-run-for-more-than-decade-with-minimum-upkeep Long-lasting flow battery could run for more than a decade with minimum upkeep], Harvard, February 9, 2017. Retrieved 13 February 2017.</ref>⏎
⏎
===As a ligand scaffold===
Chiral ferrocenyl [[phosphine]]s are employed as ligands for transition-metal catalyzed reactions. Some of them have found industrial applications in the synthesis of pharmaceuticals and agrochemicals. For example, the [[diphosphines|diphosphine]] [[1,1'-bis(diphenylphosphino)ferrocene|1,1′-bis(diphenylphosphino)ferrocene]] (dppf) is a valuable ligand for [[palladium]]-[[coupling reaction]]s.

==Derivatives and variations==
(contracted; show full)
{{Authority control}}

[[Category:Organoiron compounds]]
[[Category:Metallocenes]]
[[Category:Antiknock agents]]
[[Category:Sandwich compounds]]
[[Category:Cyclopentadienyl complexes]]